If said cleric casts that Evil spell, but does it unknowingly (e.g. mind control, or other more convoluted scenarios, perhaps involving magical sensory deprivation), are they still considered to have done an Evil act?
Yes, though it’s usually not much of an Evil act. More to the point, in most versions, clerics are prohibited from using opposed-alignment spells, which nicely insulates them from accidental alignment shifts due to spellcasting.
A good wizard, on the other hand, can actually cast protection from good (an evil spell) every day until he feels like committing horrible atrocities.
… Spells are also categorically Good or Evil?
If said cleric casts that Evil spell, but does it unknowingly (e.g. mind control, or other more convoluted scenarios, perhaps involving magical sensory deprivation), are they still considered to have done an Evil act?
Yes, though it’s usually not much of an Evil act. More to the point, in most versions, clerics are prohibited from using opposed-alignment spells, which nicely insulates them from accidental alignment shifts due to spellcasting.
A good wizard, on the other hand, can actually cast protection from good (an evil spell) every day until he feels like committing horrible atrocities.
Yes, see for example in the 3.5 SRD how “Animate Dead” has the bracketed Evil after it here.